I have run more than 12 PSI on my pro from time to time, but I can assure you it is not worth it, and actually takes away from the rideability that makes the Pro what it is. The only time you will want to run more than 11-12 PSi, is a wide open face or chute, and you had better have some good suspension underneath you, or even then, it will not be useful.
As you mentioned, you are coming off of higher HP sleds, which is fine, but I am guessing that they were also considerably heavier sleds, that do not handle as well as a Pro. If you were talking about Yamahas, then you cannot even begin to compare boost #'s, and are going to be starting over, as far as what you want/need for turbo power. If it was Cat, then you will also be dealing with a much lighter, nimbler sled. Yes, you will notice that the Cat feels more powerful with the same PSI, but you will also be able to put the power to better use on the Pro, and get further/higher/tighter. (Think Harley Vs. Crotch Rocket).
For what it is worth, I'm 205Lbs w/o clothes, so probably 240 at least all geared up, and I ride at 10PSI most of the time (when the snow is good), and rarely go above 12 anymore.